Studies of the Solid-Phase Pauson-Khand Reaction Selective in-situ Enone Reduction to 3-Azabicyclo[3.3.0]oct-anones

Daniel Becker; Daniel L. Flynn

doi:10.1016/S0040-4039(00)60352-0

Studies of the Solid-Phase Pauson-Khand Reaction Selective in-situ Enone Reduction to 3-Azabicyclo[3.3.0]oct-anones

Daniel Becker, Daniel L. Flynn

Department of Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The Smit-Caple DSAC Pauson-Khand cyclization of a series of N-protected allyl propargyl amines in the absence of oxygen gave rise to formation of the saturated azabicyclo[3.3.0]octanones in excellent yields. Standard cyclization in air gave mixtures of saturated and unsaturated ketones.

Original language	American English
Journal	Chemistry: Faculty Publications and Other Works
Volume	34
Issue number	13
DOIs	https://doi.org/10.1016/S0040-4039(00)60352-0
State	Published - Mar 26 1993

Keywords

ketones
Smit-Caple DSAC Pauson-Khand cyclization

Disciplines

Chemistry

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title = "Studies of the Solid-Phase Pauson-Khand Reaction Selective in-situ Enone Reduction to 3-Azabicyclo[3.3.0]oct-anones",

abstract = " The Smit-Caple DSAC Pauson-Khand cyclization of a series of N-protected allyl propargyl amines in the absence of oxygen gave rise to formation of the saturated azabicyclo[3.3.0]octanones in excellent yields. Standard cyclization in air gave mixtures of saturated and unsaturated ketones.",

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Y1 - 1993/3/26

N2 - The Smit-Caple DSAC Pauson-Khand cyclization of a series of N-protected allyl propargyl amines in the absence of oxygen gave rise to formation of the saturated azabicyclo[3.3.0]octanones in excellent yields. Standard cyclization in air gave mixtures of saturated and unsaturated ketones.

AB - The Smit-Caple DSAC Pauson-Khand cyclization of a series of N-protected allyl propargyl amines in the absence of oxygen gave rise to formation of the saturated azabicyclo[3.3.0]octanones in excellent yields. Standard cyclization in air gave mixtures of saturated and unsaturated ketones.

KW - ketones

KW - Smit-Caple DSAC Pauson-Khand cyclization

UR - https://ecommons.luc.edu/chemistry_facpubs/10

U2 - 10.1016/S0040-4039(00)60352-0

DO - 10.1016/S0040-4039(00)60352-0

M3 - Article

VL - 34

JO - Chemistry: Faculty Publications and Other Works

JF - Chemistry: Faculty Publications and Other Works

IS - 13

ER -

Studies of the Solid-Phase Pauson-Khand Reaction Selective in-situ Enone Reduction to 3-Azabicyclo[3.3.0]oct-anones

Abstract

Keywords

Disciplines

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