Ni-Catalyzed Borylative Diene−Aldehyde Coupling: The Remarkable Effect of P(SiMe3)3

Hee Yeon Cho; James P. Morken

doi:10.1021/JA101513D

Ni-Catalyzed Borylative Diene−Aldehyde Coupling: The Remarkable Effect of P(SiMe3)3

Boston College

Research output: Contribution to journal › Article › peer-review

Original language	American English
Journal	Journal of the American Chemical Society
Volume	132
Issue number	22
DOIs	https://doi.org/10.1021/JA101513D
State	Published - Jun 9 2010
Externally published	Yes

Disciplines

Organic Chemistry
Medicinal-Pharmaceutical Chemistry

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10.1021/JA101513DLicense: Unspecified

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title = "Ni-Catalyzed Borylative Diene−Aldehyde Coupling: The Remarkable Effect of P(SiMe3)3",

author = "Cho, {Hee Yeon} and Morken, {James P.}",

note = "The nickel-catalyzed reaction of carbonyls and dienes was accomplished in a regio- and stereoselective fashion employing a stoichiometric amount of bis(pinacolato)diboron. In the presence of P(SiMe(3))(3), this reductive coupling furnishes allyl boronic esters which are regioisomeric to those obtained with PCy(3) as the ligand.",

year = "2010",

month = jun,

day = "9",

doi = "10.1021/JA101513D",

language = "American English",

volume = "132",

journal = "Journal of the American Chemical Society",

number = "22",

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TY - JOUR

T1 - Ni-Catalyzed Borylative Diene−Aldehyde Coupling: The Remarkable Effect of P(SiMe3)3

AU - Cho, Hee Yeon

AU - Morken, James P.

N1 - The nickel-catalyzed reaction of carbonyls and dienes was accomplished in a regio- and stereoselective fashion employing a stoichiometric amount of bis(pinacolato)diboron. In the presence of P(SiMe(3))(3), this reductive coupling furnishes allyl boronic esters which are regioisomeric to those obtained with PCy(3) as the ligand.

PY - 2010/6/9

Y1 - 2010/6/9

UR - http://europepmc.org/articles/PMC2912217

U2 - 10.1021/JA101513D

DO - 10.1021/JA101513D

M3 - Article

VL - 132

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 22

ER -

Ni-Catalyzed Borylative Diene−Aldehyde Coupling: The Remarkable Effect of P(SiMe3)3

Disciplines

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